Artículo

Synthesis of new mixed (-)-menthylalkyltin dihydrides. stereoselective reduction of chiral and prochiral ketones

Terraza, Victor Fabricio; Gerbino, Darío CésarIcon ; Podestá, Julio CesarIcon
Fecha de publicación: 03/2021
Editorial: Elsevier Science SA
Revista: Journal of Organometallic Chemistry
ISSN: 0022-328X
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

This paper reports de synthesis of a series of (-)-menthylalkyltin dihydrides, (-)-MenRSnH2 (R = Me, nBu, i-Pr, t-Bu, Neophyl), starting from (-)-menthyltrimethyltin. The new (-)-menthylalkyltin dihydrides12–16 were used in a study on the stereoselective reduction of chiral (-)-menthone under differentreaction conditions. Also the results obtained in the reductions of prochiral acetophenone (27) and 2-acetylnaphthalene (28), with (-)-menthylmethyl- (12) and (-)-menthyli-propyltin (14) dihydrides are informed. Some physical properties as well as full 1H-, 13C-, and 119Sn NMR data of the new organotin compounds are informed.
Palabras clave: (-)-menthylalkyltin dihydrides , Use in stereoselective reductions , Reduction of (-)-menthone , Reduction of acetophenone, Reduction of 2-acetylnaphthalene
 
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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/255700
URL: https://linkinghub.elsevier.com/retrieve/pii/S0022328X21000012
DOI: http://dx.doi.org/10.1016/j.jorganchem.2021.121680
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Citación
Terraza, Victor Fabricio; Gerbino, Darío César; Podestá, Julio Cesar; Synthesis of new mixed (-)-menthylalkyltin dihydrides. stereoselective reduction of chiral and prochiral ketones; Elsevier Science SA; Journal of Organometallic Chemistry; 935; 3-2021; 1-9
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