Artículo

The non-metathetic role of Grubbs’ carbene complexes: From hydrogen-free reduction of α,β-unsaturated alkenes to solid-supported sequential cross-metathesis/reduction

Poeylaut Palena, Andrés AlbertoIcon ; Testero, Sebastian AndresIcon ; Mata, Ernesto GabinoIcon
Fecha de publicación: 02/2011
Editorial: Royal Society of Chemistry
Revista: Chemical Communications
ISSN: 1359-7345
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

An efficient and high-yielding “hydrogen-free” reduction of α,β-unsaturated alkenes was carried out employing Grubbs' catalyst in a non-metathetic role and Et3SiH. Conditions were optimized under microwave irradiation. Application to the solid-phase organic synthesis allows a facile construction of sp3–sp3 carbon bonds through a sequential cross metathesis/olefin reduction.
Palabras clave: hydrogen free-reduction , Grubbs catalyst , sequential cross-metathesis/reduction , Solid Phase
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/128082
URL: https://pubs.rsc.org/en/content/articlelanding/2011/cc/c0cc04115g#!divAbstract
DOI: http://dx.doi.org/10.1039/C0CC04115G
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Articulos(IQUIR)
Articulos de INST.DE QUIMICA ROSARIO
Citación
Poeylaut Palena, Andrés Alberto; Testero, Sebastian Andres; Mata, Ernesto Gabino; The non-metathetic role of Grubbs’ carbene complexes: From hydrogen-free reduction of α,β-unsaturated alkenes to solid-supported sequential cross-metathesis/reduction; Royal Society of Chemistry; Chemical Communications; 47; 5; 2-2011; 1565-1567
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