Layered double hydroxides modified by transition metals for sustainable glycerol valorization to glycerol carbonate

Abstract

The surplus of glycerol generated as a by-product in biodiesel production increased interest in the investigation of the catalytic conversion of this platform molecule into valuable chemical products, such as glycerol carbonate. Therefore, the catalytic transesterification of glycerol and dimethyl carbonate for the synthesis of glycerol carbonate was studied using Cu-Zn-Mg-Al mixed oxide catalysts with different Cu-Zn atomic ratios. Layered double hydroxides were the precursors materials to obtain multi metallic oxides. They were synthesized by coprecipitation. The materials were physico-chemically characterized by XRD, MP-AES, N2 sorption, SEM, XPS and TPD-CO2. The addition of Cu and Zn to the Mg and Al matrix improved the catalytic behaviour of the solid materials. First, the highest glycerol carbonate yield was reached with the catalyst with the highest Zn load at 70 °C for 90 min. This result was taken as a basis to modify parameters and find the optimal reaction conditions. They were a temperature of 85 °C, a reaction time of 270 min, a DMC:glycerol molar ratio of 2:1, solvent free and 7.5 wt% of catalyst. The highest yield obtained (82%) was attributable to the synergistic effect of the Cu-Zn load promoted by an adequate distribution of basicity and textural properties. The reuses of the best catalyst were also investigated.