The radical-based reduction with (TMS)3SiH 'on water'

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dc.conicet.fuenteindividual
dc.conicet.organizacionUniversidad de Buenos Aires. Facultad de Farmacia y Bioquímica
dc.conicet.organizacionConsejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay
dc.conicet.organizacionConsiglio Nazionale delle Ricerche
dc.conicet.organizacionConsiglio Nazionale delle Ricerche
dc.conicet.organizacionConsiglio Nazionale delle Ricerche
dc.conicet.paisOrganizacionArgentina
dc.conicet.paisOrganizacionArgentina
dc.conicet.paisOrganizacionItalia
dc.conicet.paisOrganizacionItalia
dc.conicet.paisOrganizacionItalia
dc.conicet.produccionid6289989
dc.contributor.authorPostigo, Jose Alberto
dc.contributor.authorFerreri, Carla
dc.contributor.authorNavacchia, Maria Luisa
dc.contributor.authorChatgilialoglu, Chryssostomos
dc.date.accessioned2021-11-29T12:09:06Z
dc.date.available2021-11-29T12:09:06Z
dc.date.issued2005-12
dc.date.updated2021-07-26T17:16:41Z
dc.description.abstractReduction of different organohalides, bromonucleosides among them, was successfully carried out in yields ranging from 75% to quantitative, using (TMS)3SiH in a heterogeneous system with water as the solvent. Our procedure, employing 2-mercaptoethanol as the catalyst and the hydrophobic diazo-compound ACCN as the initiator, illustrates that (TMS)3SiH can be the radical-based reducing agent of choice in aqueous medium. (TMS) 3SiH does not suffer from any significant reaction with water and can safely be used with additional benefit, such as ease of purification and environmental compatibility.es
dc.description.filFil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
dc.description.filFil: Ferreri, Carla. Consiglio Nazionale delle Ricerche; Italia
dc.description.filFil: Navacchia, Maria Luisa. Consiglio Nazionale delle Ricerche; Italia
dc.description.filFil: Chatgilialoglu, Chryssostomos. Consiglio Nazionale delle Ricerche; Italia
dc.formatapplication/pdfes
dc.identifier.citationPostigo, Jose Alberto; Ferreri, Carla; Navacchia, Maria Luisa; Chatgilialoglu, Chryssostomos; The radical-based reduction with (TMS)3SiH 'on water'; Georg Thieme Verlag Kg; Synlett; 18; 12-2005; 2854-2856es
dc.identifier.institucionalCONICET
dc.identifier.issn0936-5214es
dc.identifier.repoCONICET Digital
dc.identifier.urihttp://hdl.handle.net/11336/147592
dc.journal.ciudadStuttgartes
dc.journal.number18es
dc.journal.pagination2854-2856es
dc.journal.paisAlemaniaes
dc.journal.titleSynlettes
dc.language.isoenges
dc.publisherGeorg Thieme Verlag Kges
dc.relation.alternativeidinfo:eu-repo/semantics/altIdentifier/url/https://www.thieme-connect.com/ejournals/abstract/synlett/doi/10.1055/s-2005-918917
dc.relation.alternativeidinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1055/s-2005-918917
dc.rightsinfo:eu-repo/semantics/openAccess*
dc.rights.urihttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/*
dc.subjectAZO COMPOUNDSes
dc.subjectRADICAL REACTIONSes
dc.subjectREDUCTIONSes
dc.subjectTHIOLSes
dc.subjectTRIS(TRIMETHYLSILYL)SILANEes
dc.subject.classificationQuímica Orgánicaes
dc.subject.classificationCiencias Químicases
dc.subject.classificationCIENCIAS NATURALES Y EXACTASes
dc.titleThe radical-based reduction with (TMS)3SiH 'on water'es
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion

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