Oxygen Evolution Nickel Hydroxide Electrodes in a Ni-MH Battery Prototype
; Cuscueta, Diego Javier
; Salva, Horacio Ramon
; Rodríguez Nieto, Felipe Jorge ; Ghilarducci, Ada Albertina
; Visintin, Arnaldo 
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Fecha
05/2012
Editorial
Ecole Polytechnique de Montreal
Revista
Journal Of New Materials For Electrochemical Systems
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Institución organizadora
ISSN
1480-2422
eISSN
ISBN
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Inglés
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Resumen
The effect of cobalt in both alpha and beta phases on the oxygen evolution of nickel hydroxide was studied. The electrochemical properties of the oxygen evolution reaction on the positive nickel hydroxide electrodes were studied under conditions similar to those of a commercial Ni-MH battery. The presence of different kinds of defects in the structure of the active material was determined by XRD methods distorted and asymmetric reflections in the XRD patterns. Both the morphology of the active material and the additives influence the oxygen evolution potential and the electrochemical characteristics. The experimental results showed that the optimized prototype used in this work is suitable for evaluating several electrochemical parameters. It was shown that the electrode without cobalt exhibited the charging efficiency was 94% and those with cobalt exhibited a charging of 98%.
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