Atomistic Insights into Chemical Interface Damping of Surface Plasmon Excitations in Silver Nanoclusters

Abstract

A detailed description of the mechanism underlying chemical interface damping (CID) in silver nanoclusters is presented. The effect of adsorbates on the surface plasmon excitation in silver nanoclusters is explored by means of a method based on time-dependent self-consistent charge density functional tight binding (TD-SCC-DFTB). By using this tool, we have calculated the homogeneous line width of the surface plasmon resonance (SPR) band for both naked and capped silver nanoclusters. A new picture explaining the decreased lifetime of the surface plasmon excitations is provided, in which coupling between particles states via adsorbate states enhances the natural dephasing mechanism of the surface plasmon excitation. To the best of our knowledge, this is the first report that addresses this topic from a fully atomistic time-dependent approach considering nanosized particles.