Study of the light-induced metal-insulator transition in SrTiO3 by photoresistance spectroscopy

Abstract

Photoresistivity and its spectral response has been systematically studied in oxygen deficient SrTiO3 single crystals for a wide range of resistivities, ρ, and carrier densities, n. At roomtemperature we have found a persistent photoresistance that gradually decreases as ρ is diminished or n is increased in addition to relaxation times of seconds to a few minutes suggesting that trapping of carriers is playing a major role. An analysis of the photoresistance excitation spectra shows two distinctive features that are related to the indirect gap of SrTiO3 at (3.25 ± 0.04) eV and to a direct transition at (3.40 ± 0.03) eV. The photoresistive crystals present a temperature dependent resisitivity under illumination that experiences a metal-insulator transition below T ∼ 85 K. Lowtemperature photoresistance spectrum reveals as a suitable technique to understand the origin of this transition, pointing to an enhanced efficiency of the ∼ 3.25 eV gap to promote electrons to the bottom of the conduction band.