Heat capacity of periodically driven two-level systems

Abstract

We define the heat capacity for steady periodically driven systems and as an example we compute it for dissipative two-level systems where the energy gap is time-modulated. There, as a function of ambient temperature, the Schottky peak remains the dominant feature. Yet, in contrast with equilibrium, the quasistatic thermal response of a nonequilibrium system also reveals kinetic information present in the transition rates; e.g., the heat capacity depends on the time-symmetric reactivities and changes by the presence of a kinetic barrier. It still vanishes though at absolute zero, in accord with an extended Nernst heat postulate, but at a different rate from the equilibrium case. More generally, we discuss the dependence on driving frequency and amplitude.