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dc.contributor.author
Jiang, Hui  
dc.contributor.author
Bellomo Peraza, Ana Ines  
dc.contributor.author
Zhang, Mengnan  
dc.contributor.author
Carroll, Patrick J.  
dc.contributor.author
Manor, Brian C.  
dc.contributor.author
Jia, Tiezheng  
dc.contributor.author
Walsh, Patrick J.  
dc.date.available
2020-03-06T19:58:20Z  
dc.date.issued
2018-05  
dc.identifier.citation
Jiang, Hui; Bellomo Peraza, Ana Ines; Zhang, Mengnan; Carroll, Patrick J.; Manor, Brian C.; et al.; Palladium-Catalyzed Direct C-H Arylation of 3-(Methylsulfinyl)thiophenes; American Chemical Society; Organic Letters; 20; 9; 5-2018; 2522-2525  
dc.identifier.issn
1523-7060  
dc.identifier.uri
http://hdl.handle.net/11336/98977  
dc.description.abstract
A palladium-catalyzed direct arylation of (3-thiophene)S(O)Me derivatives has been developed. This protocol is effective for the selective synthesis of 2-arylated and 2,5-diarylated sulfinylthiophene derivatives with as low as 0.5 mol % catalyst loading. Various functional groups are well tolerated. A method to install two different aryl groups on 3-(methylsulfinyl)thiophenes is also introduced.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
American Chemical Society  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
DIRECT ARYLATION  
dc.subject
HIGH THROUGHPUT SCREENING  
dc.subject
SULFINYL THIOPHENES  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Palladium-Catalyzed Direct C-H Arylation of 3-(Methylsulfinyl)thiophenes  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2020-03-04T15:41:33Z  
dc.journal.volume
20  
dc.journal.number
9  
dc.journal.pagination
2522-2525  
dc.journal.pais
Estados Unidos  
dc.description.fil
Fil: Jiang, Hui. University of Pennsylvania; Estados Unidos. Southern University Of Science And Technology; China  
dc.description.fil
Fil: Bellomo Peraza, Ana Ines. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. University of Pennsylvania; Estados Unidos  
dc.description.fil
Fil: Zhang, Mengnan. University of Pennsylvania; Estados Unidos  
dc.description.fil
Fil: Carroll, Patrick J.. University of Pennsylvania; Estados Unidos  
dc.description.fil
Fil: Manor, Brian C.. University of Pennsylvania; Estados Unidos  
dc.description.fil
Fil: Jia, Tiezheng. Southern University Of Science And Technology; China  
dc.description.fil
Fil: Walsh, Patrick J.. University of Pennsylvania; Estados Unidos  
dc.journal.title
Organic Letters  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.orglett.8b00599  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.orglett.8b00599  

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