Artículo

Gas phase structure of diiodosilane SiH2I2

Ben Altabef, AídaIcon ; H. Oberhammer
Fecha de publicación: 11/2002
Editorial: Elsevier Science
Revista: Journal of Molecular Structure
ISSN: 0022-2860
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The molecular structure of diiodosilane has been determined by gas electron diffraction. Assuming C2v symmetry, only the S-I bond length (2.423(3) Å) and the I-Si-I bond angle (110.8(4)°) could be determined accurately in this experiment. The experimental geometric parameters and vibrational frequencies which were reported earlier are compared to calculated values derived with the HF approximation and DFT methods (B3LYP and SVWN) using 3-21G* basis sets and effective core potentials.
Palabras clave: Diiodosilane , Gas Electron Diffraction , Infrared Spectra , Quantum Chemical Calculations
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/62130
DOI: https://doi.org/10.1016/S0022-2860(02)00354-X
URL: https://www.sciencedirect.com/science/article/pii/S002228600200354X
Colecciones
Articulos(INQUINOA)
Articulos de INST.DE QUIMICA DEL NOROESTE
Citación
Ben Altabef, Aída; H. Oberhammer; Gas phase structure of diiodosilane SiH2I2; Elsevier Science; Journal of Molecular Structure; 641; 2-3; 11-2002; 259-261
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