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dc.contributor.author
Novaes, Luiz F. T.  
dc.contributor.author
Sarotti, Ariel Marcelo  
dc.contributor.author
Pilli, Ronaldo A.  
dc.date.available
2016-06-03T21:22:00Z  
dc.date.issued
2015-06  
dc.identifier.citation
Novaes, Luiz F. T.; Sarotti, Ariel Marcelo; Pilli, Ronaldo A.; Total Synthesis and Structural Elucidation of Cryptolatifolione; Royal Society of Chemistry; RSC Advances; 5; 66; 6-2015; 53471-53476  
dc.identifier.issn
2046-2069  
dc.identifier.uri
http://hdl.handle.net/11336/6046  
dc.description.abstract
An enantioselective total synthesis of Cryptolatifolione and its C-8 epimer is presented in a protecting-group-free fashion. The synthesis relied on the use of a catalytic double Krische allylation, catalytic olefin metathesis and a C-H oxidation. Comparison of spectroscopical data of the synthetic isomers and natural product made possible the unequivocally elucidation of the absolute configuration of Cryptolatifolione.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Royal Society of Chemistry  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc/2.5/ar/  
dc.subject
Total Synthesis  
dc.subject
Cryptolatilfolione  
dc.subject
Stereochemical Assignment  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Total Synthesis and Structural Elucidation of Cryptolatifolione  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2016-06-01T14:05:47Z  
dc.journal.volume
5  
dc.journal.number
66  
dc.journal.pagination
53471-53476  
dc.journal.pais
Reino Unido  
dc.journal.ciudad
Londres  
dc.description.fil
Fil: Novaes, Luiz F. T.. Universidade Estadual de Campinas; Brasil  
dc.description.fil
Fil: Sarotti, Ariel Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina  
dc.description.fil
Fil: Pilli, Ronaldo A.. Universidade Estadual de Campinas; Brasil  
dc.journal.title
RSC Advances  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/C5RA09186A  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/C5RA09186A  

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