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dc.contributor.author
Brito, Gilmar A.  
dc.contributor.author
Sarotti, Ariel Marcelo  
dc.contributor.author
Wipf, Peter  
dc.contributor.author
Pilli, Ronaldo A.  
dc.date.available
2016-06-01T15:45:21Z  
dc.date.issued
2015-10  
dc.identifier.citation
Brito, Gilmar A.; Sarotti, Ariel Marcelo; Wipf, Peter; Pilli, Ronaldo A.; Cascade cyclization triggered by imine formation. Formal synthesis of the alkaloid (±)-stemoamide and its 9a-epimer; Elsevier; Tetrahedron Letters; 56; 48; 10-2015; 6664-6668  
dc.identifier.issn
0040-4039  
dc.identifier.uri
http://hdl.handle.net/11336/5987  
dc.description.abstract
A concise formal synthesis of stemoamide ( 1) and its 9a-epimer 14in 5 steps is described featuring a cas-cade cyclization triggered by imine formation. A good selectivity for either epimer is readily accom-plished by variation of the ester ( 9bor 9a, respectively) and the reaction conditions.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/  
dc.subject
Cascade Cyclization  
dc.subject
Imine  
dc.subject
Formal Synthesis  
dc.subject
Stemoamide  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Cascade cyclization triggered by imine formation. Formal synthesis of the alkaloid (±)-stemoamide and its 9a-epimer  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2016-06-01T13:49:16Z  
dc.journal.volume
56  
dc.journal.number
48  
dc.journal.pagination
6664-6668  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Brito, Gilmar A.. Universidade Estadual de Campinas; Brasil  
dc.description.fil
Fil: Sarotti, Ariel Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina  
dc.description.fil
Fil: Wipf, Peter. Univeristy Of Pittsburgh; Estados Unidos  
dc.description.fil
Fil: Pilli, Ronaldo A.. Universidade Estadual de Campinas; Brasil  
dc.journal.title
Tetrahedron Letters  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0040403915302148  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tetlet.2015.10.017  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.tetlet.2015.10.017  

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