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dc.contributor.author
Tan, Eric  
dc.contributor.author
Konovalov, Andrey I.  
dc.contributor.author
Fernandez, Gabriela Araceli  
dc.contributor.author
Dorel, Ruth  
dc.contributor.author
Echavarren, Antonio M.  
dc.date.available
2018-06-28T14:05:07Z  
dc.date.issued
2017-10  
dc.identifier.citation
Tan, Eric; Konovalov, Andrey I.; Fernandez, Gabriela Araceli; Dorel, Ruth; Echavarren, Antonio M.; Ruthenium-Catalyzed Peri- and Ortho-Alkynylation with Bromoalkynes via Insertion and Elimination; American Chemical Society; Organic Letters; 19; 20; 10-2017; 5561-5564  
dc.identifier.issn
1523-7060  
dc.identifier.uri
http://hdl.handle.net/11336/50324  
dc.description.abstract
The alkynylation of naphthols takes place with total regiocontrol at the peri position of the hydroxyl group in the presence of [RuCl2(p-cymene)]2 as the catalyst. This reaction features high functional group tolerance. The related ortho-alkynylation of benzoic acids proceeds under similar conditions and also shows wide functional group tolerance. Both reactions proceed through metalation, insertion of the alkyne, and bromide elimination.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
American Chemical Society  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by/2.5/ar/  
dc.subject
Ruthenium Catalyst  
dc.subject
Alkynylation  
dc.subject
Naphtols  
dc.subject
Benzoic Acids  
dc.subject.classification
Otras Ciencias Químicas  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Ruthenium-Catalyzed Peri- and Ortho-Alkynylation with Bromoalkynes via Insertion and Elimination  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2018-06-19T15:56:35Z  
dc.journal.volume
19  
dc.journal.number
20  
dc.journal.pagination
5561-5564  
dc.journal.pais
Estados Unidos  
dc.journal.ciudad
Maryland  
dc.description.fil
Fil: Tan, Eric. Institut Català d'Investigació Química; España  
dc.description.fil
Fil: Konovalov, Andrey I.. Institut Català d'Investigació Química; España  
dc.description.fil
Fil: Fernandez, Gabriela Araceli. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias ; Argentina. Institut Català d'Investigació Química; España  
dc.description.fil
Fil: Dorel, Ruth. Institut Català d'Investigació Química; España  
dc.description.fil
Fil: Echavarren, Antonio M.. Universitat Rovira I Virgili; España. Institut Català d'Investigació Química; España  
dc.journal.title
Organic Letters  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.orglett.7b02655  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.orglett.7b02655  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5679662/  

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