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dc.contributor.author
Fenoy, Gonzalo Eduardo  
dc.contributor.author
Lorenz, Christoph  
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Pasquale, Miguel Angel  
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Marmisollé, Waldemar Alejandro  
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Bäuerle, Peter  
dc.contributor.author
Azzaroni, Omar  
dc.contributor.author
Knoll, Wolfgang  
dc.date.available
2025-05-26T10:18:16Z  
dc.date.issued
2024-07  
dc.identifier.citation
Fenoy, Gonzalo Eduardo; Lorenz, Christoph; Pasquale, Miguel Angel; Marmisollé, Waldemar Alejandro; Bäuerle, Peter; et al.; A Poly(3,4-ethylenedioxythiophene) Derivative Incorporating Ethynyl Moieties for Click Chemistry-Based Bioelectronics; American Chemical Society; Chemistry Of Materials; 36; 15; 7-2024; 7207-7221  
dc.identifier.issn
0897-4756  
dc.identifier.uri
http://hdl.handle.net/11336/262530  
dc.description.abstract
Efficiently integrating biological elements with the surface of organic semiconductors is a key objective in advancing the development of bioelectronic devices. In this work, we introduce the fabrication and functionalization of organic electrochemical transistors (OECTs) utilizing PEDOT-E as channel material, a poly(3,4-ethylenedioxythiophene) (PEDOT) derivative featuring pendant ethynyl moieties. First, the synthesis of the EDOT-E monomer and its electropolymerization onto Au interdigitated electrodes to produce PEDOT-E OECTs are detailed. Next, the film growth process is investigated by varying the number of electropolymerization cycles, leading to the optimization of the transistor fabrication protocol. The obtained devices exhibit lower threshold voltage values compared with state-of-the-art PEDOT-based OECTs. Furthermore, the ethynyl moieties are exploited for the click chemistry-based functionalization of the devices, enabling the incorporation of ferrocene redox probes. Next, biorecognition elements such as an azide-functionalized biotin are also anchored, yielding the acquisition of robust bioconstructs based on avidin–biotin interactions that are suitable for enzymatic biosensing. Last, azido-functionalized gelatin is “clicked” onto the transistors, not only enhancing their electronic features but also improving their biocompatibility for cell interfacing, a crucial step toward the further development of neural probes.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
American Chemical Society  
dc.rights
info:eu-repo/semantics/restrictedAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Electrodes  
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Transistors  
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Polymers  
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Electropolymerization  
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Físico-Química, Ciencia de los Polímeros, Electroquímica  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
A Poly(3,4-ethylenedioxythiophene) Derivative Incorporating Ethynyl Moieties for Click Chemistry-Based Bioelectronics  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2025-05-26T09:34:33Z  
dc.journal.volume
36  
dc.journal.number
15  
dc.journal.pagination
7207-7221  
dc.journal.pais
Estados Unidos  
dc.description.fil
Fil: Fenoy, Gonzalo Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina  
dc.description.fil
Fil: Lorenz, Christoph. Universitat Ulm; Alemania  
dc.description.fil
Fil: Pasquale, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina  
dc.description.fil
Fil: Marmisollé, Waldemar Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina  
dc.description.fil
Fil: Bäuerle, Peter. Universitat Ulm; Alemania  
dc.description.fil
Fil: Azzaroni, Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina  
dc.description.fil
Fil: Knoll, Wolfgang. Universitat Ulm; Alemania  
dc.journal.title
Chemistry Of Materials  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.4c00989  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.chemmater.4c00989