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dc.contributor.author
Malunavar, Shruti S.
dc.contributor.author
Anchi, Athmanand
dc.contributor.author
Prabhala, Pavankumar
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Kalkhambkar, Rajesh G.
dc.contributor.author
Borosky, Gabriela Leonor
dc.contributor.author
Laali, Kenneth K.
dc.date.available
2023-11-14T17:17:22Z
dc.date.issued
2022-08-17
dc.identifier.citation
Malunavar, Shruti S.; Anchi, Athmanand; Prabhala, Pavankumar; Kalkhambkar, Rajesh G.; Borosky, Gabriela Leonor; et al.; N-ethyltetramethylguanidinium ionic liquid [ETMG][EtSO3] as organocatalyst and solvent for facile amide synthesis by formyl-transfer with N-formyl-saccharin; Pergamon-Elsevier Science Ltd; Tetrahedron Letters; 104; 17-8-2022; 1-6
dc.identifier.issn
0040-4039
dc.identifier.uri
http://hdl.handle.net/11336/218083
dc.description.abstract
We report a simple and highly efficient, acid and metal free, method for the synthesis of libraries of primary and secondary formamides employing N-ethyltetramethylguanidinium IL, [ETMG][EtOSO3] as dual organocatalyst and solvent, and N-formyl-saccharin (N-formyl-SAC) as formyl-transfer agent. Good to excellent isolated yields are achieved at r.t. within minutes under sonication. A rational for the efficacy of this organocatalyst is provided by DFT computations.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Pergamon-Elsevier Science Ltd
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
AMIDE SYNTHESIS
dc.subject
DFT COMPUTATIONS
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N-ETHYLTETRAMETHYLGUANIDINIUM SALT AS ORGANOCATALYST
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N-FORMYL-SAC
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RECYCLING/REUSE
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Química Orgánica
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
N-ethyltetramethylguanidinium ionic liquid [ETMG][EtSO3] as organocatalyst and solvent for facile amide synthesis by formyl-transfer with N-formyl-saccharin
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2023-11-14T14:31:24Z
dc.journal.volume
104
dc.journal.pagination
1-6
dc.journal.pais
Estados Unidos
dc.description.fil
Fil: Malunavar, Shruti S.. Karnatak University; India
dc.description.fil
Fil: Anchi, Athmanand. Karnatak University; India
dc.description.fil
Fil: Prabhala, Pavankumar. Karnatak University; India
dc.description.fil
Fil: Kalkhambkar, Rajesh G.. Karnatak University; India
dc.description.fil
Fil: Borosky, Gabriela Leonor. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
dc.description.fil
Fil: Laali, Kenneth K.. University Of North Florida; Estados Unidos
dc.journal.title
Tetrahedron Letters
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.tetlet.2022.153990
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