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dc.contributor.author
Anchi, Athmanand  
dc.contributor.author
Sutar, Suraj M.  
dc.contributor.author
Kalkhambkar, Rajesh G.  
dc.contributor.author
Borosky, Gabriela Leonor  
dc.contributor.author
Laali, Kenneth K.  
dc.date.available
2023-11-09T12:41:17Z  
dc.date.issued
2022-09  
dc.identifier.citation
Anchi, Athmanand; Sutar, Suraj M.; Kalkhambkar, Rajesh G.; Borosky, Gabriela Leonor; Laali, Kenneth K.; Tropylium-BF4 as Organocatalyst for Efficient Synthesis of Nitriles from Aldoximes; Synthetic Scope and Mechanistic Insights; John Wiley & Sons; ChemistrySelect; 7; 35; 9-2022; 1-9  
dc.identifier.issn
2365-6549  
dc.identifier.uri
http://hdl.handle.net/11336/217600  
dc.description.abstract
Structurally diverse aldoximes were conveniently transformed within minutes to the corresponding nitriles by using tropylium BF4 as organocatalyst, in 1-butyl-3-methylimidazolium ionic liquids (BMIM-ILs) as solvent, under microwave irradiation. The scope of this convenient, cyanide free, process for nitrile synthesis was explored, and DFT computations were employed to shed light on the mechanistic steps of this catalytic reaction leading to dehydration.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
John Wiley & Sons  
dc.rights
info:eu-repo/semantics/restrictedAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
ALDOXIME TO NITRILE  
dc.subject
DFT COMPUTATIONS  
dc.subject
IONIC LIQUIDS  
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ORGANOCATALYST  
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TROPYLIUM  
dc.subject.classification
Química Orgánica  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Tropylium-BF4 as Organocatalyst for Efficient Synthesis of Nitriles from Aldoximes; Synthetic Scope and Mechanistic Insights  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2023-11-07T14:29:37Z  
dc.journal.volume
7  
dc.journal.number
35  
dc.journal.pagination
1-9  
dc.journal.pais
Alemania  
dc.description.fil
Fil: Anchi, Athmanand. Karnatak University; India  
dc.description.fil
Fil: Sutar, Suraj M.. Karnatak University; India  
dc.description.fil
Fil: Kalkhambkar, Rajesh G.. Karnatak University; India  
dc.description.fil
Fil: Borosky, Gabriela Leonor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina  
dc.description.fil
Fil: Laali, Kenneth K.. University of Florida; Estados Unidos  
dc.journal.title
ChemistrySelect  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/slct.202202791  

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