Artículo

Tropylium-BF4 as Organocatalyst for Efficient Synthesis of Nitriles from Aldoximes; Synthetic Scope and Mechanistic Insights

Anchi, Athmanand; Sutar, Suraj M.; Kalkhambkar, Rajesh G.; Borosky, Gabriela LeonorIcon ; Laali, Kenneth K.
Fecha de publicación: 09/2022
Editorial: John Wiley & Sons
Revista: ChemistrySelect
ISSN: 2365-6549
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Structurally diverse aldoximes were conveniently transformed within minutes to the corresponding nitriles by using tropylium BF4 as organocatalyst, in 1-butyl-3-methylimidazolium ionic liquids (BMIM-ILs) as solvent, under microwave irradiation. The scope of this convenient, cyanide free, process for nitrile synthesis was explored, and DFT computations were employed to shed light on the mechanistic steps of this catalytic reaction leading to dehydration.
Palabras clave: ALDOXIME TO NITRILE , DFT COMPUTATIONS , IONIC LIQUIDS , ORGANOCATALYST , TROPYLIUM
 
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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/217600
DOI: http://dx.doi.org/10.1002/slct.202202791
Colecciones
Articulos(INFIQC)
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Citación
Anchi, Athmanand; Sutar, Suraj M.; Kalkhambkar, Rajesh G.; Borosky, Gabriela Leonor; Laali, Kenneth K.; Tropylium-BF4 as Organocatalyst for Efficient Synthesis of Nitriles from Aldoximes; Synthetic Scope and Mechanistic Insights; John Wiley & Sons; ChemistrySelect; 7; 35; 9-2022; 1-9
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