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dc.contributor.author
Guastavino, Javier Fernando  
dc.contributor.author
Rossi, Roberto Arturo  
dc.date.available
2017-08-01T14:50:05Z  
dc.date.issued
2009-12  
dc.identifier.citation
Guastavino, Javier Fernando; Rossi, Roberto Arturo; Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism; American Chemical Society; Organometallics; 28; 8; 12-2009; 2646-2649  
dc.identifier.issn
0276-7333  
dc.identifier.uri
http://hdl.handle.net/11336/21698  
dc.description.abstract
The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
American Chemical Society  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
1,1-Dichlorocyclopropanes  
dc.subject
Srn1 Reaction  
dc.subject
1,1-Bis(Trimethylstannyl)Cyclopropanes  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2017-07-28T15:15:19Z  
dc.journal.volume
28  
dc.journal.number
8  
dc.journal.pagination
2646-2649  
dc.journal.pais
Estados Unidos  
dc.journal.ciudad
Washington  
dc.description.fil
Fil: Guastavino, Javier Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina  
dc.description.fil
Fil: Rossi, Roberto Arturo. Universidad Nacional de Córdoba; Argentina  
dc.journal.title
Organometallics  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/om801104e  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/om801104e  

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