Artículo

Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism

Guastavino, Javier FernandoIcon ; Rossi, Roberto ArturoIcon
Fecha de publicación: 12/2009
Editorial: American Chemical Society
Revista: Organometallics
ISSN: 0276-7333
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield.
Palabras clave: 1,1-Dichlorocyclopropanes , Srn1 Reaction , 1,1-Bis(Trimethylstannyl)Cyclopropanes
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/21698
DOI: http://dx.doi.org/10.1021/om801104e
URL: http://pubs.acs.org/doi/abs/10.1021/om801104e
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Articulos(INTEC)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Guastavino, Javier Fernando; Rossi, Roberto Arturo; Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism; American Chemical Society; Organometallics; 28; 8; 12-2009; 2646-2649
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