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dc.contributor.author
Cobos, Carlos Jorge  
dc.contributor.author
Sölter, Lars  
dc.contributor.author
Tellbach, Elsa  
dc.contributor.author
Troe, Jürgen  
dc.date.available
2023-07-21T20:23:04Z  
dc.date.issued
2022-12  
dc.identifier.citation
Cobos, Carlos Jorge; Sölter, Lars; Tellbach, Elsa; Troe, Jürgen; The Thermal Dissociation-Recombination Reactions of SiF4, SiF3, and SiF2: A Shock Wave and Theoretical Modeling Study; American Chemical Society; Journal of Physical Chemistry A; 126; 47; 12-2022; 8871-8877  
dc.identifier.issn
1089-5639  
dc.identifier.uri
http://hdl.handle.net/11336/204885  
dc.description.abstract
Monitoring UV absorption signals of SiF2and SiF, the thermal dissociation reactions of SiF4and SiF2were studied in shock waves. Rationalizing the experimental observations by standard unimolecular rate theory in combination with quantum-chemical calculations of the reaction potentials, rate constants for the thermal dissociation reactions of SiF4, SiF3, and SiF2and their reverse recombination reactions were determined over broad temperature and pressure ranges. A comparison of fluorosilicon and fluorocarbon chemistry was finally made.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
American Chemical Society  
dc.rights
info:eu-repo/semantics/restrictedAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
-  
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
The Thermal Dissociation-Recombination Reactions of SiF4, SiF3, and SiF2: A Shock Wave and Theoretical Modeling Study  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2023-07-05T12:16:46Z  
dc.journal.volume
126  
dc.journal.number
47  
dc.journal.pagination
8871-8877  
dc.journal.pais
Estados Unidos  
dc.description.fil
Fil: Cobos, Carlos Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina  
dc.description.fil
Fil: Sölter, Lars. Universität Göttingen; Alemania. Max-Planck-Institut für Multidisziplinäre Naturwissenschaften; Alemania  
dc.description.fil
Fil: Tellbach, Elsa. Universität Göttingen; Alemania. Max-Planck-Institut für Multidisziplinäre Naturwissenschaften; Alemania  
dc.description.fil
Fil: Troe, Jürgen. Universität Göttingen; Alemania. Max-Planck-Institut für Multidisziplinäre Naturwissenschaften; Alemania  
dc.journal.title
Journal of Physical Chemistry A  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.jpca.2c06529  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.jpca.2c06529  

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