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dc.contributor.author
Jiang, Dong  
dc.contributor.author
Barata Vallejo, Sebastian  
dc.contributor.author
Golding, Bernard T.  
dc.contributor.author
Ferreri, Carla  
dc.contributor.author
Chatgilialoglu, Chryssostomos  
dc.date.available
2023-04-20T12:02:11Z  
dc.date.issued
2012-02  
dc.identifier.citation
Jiang, Dong; Barata Vallejo, Sebastian; Golding, Bernard T.; Ferreri, Carla; Chatgilialoglu, Chryssostomos; Revisiting the reaction of hydroxyl radicals with vicinal diols in water; Royal Society of Chemistry; Organic & Biomolecular Chemistry; 10; 5; 2-2012; 1102-1107  
dc.identifier.issn
1477-0520  
dc.identifier.uri
http://hdl.handle.net/11336/194698  
dc.description.abstract
The carbonyl products of the reactions of hydroxyl radicals with three vicinal diols (ethane-1,2-diol, propane-1,2-diol and butane-2,3-diol) have been identified and quantified. Hydroxyl radicals were produced by gamma-radiolysis of N2O-saturated aqueous solutions. The reactions result in the formation of alkoxyl radicals (15%) followed by beta-fragmentation, and alpha-hydroxyl alkyl radicals that undergo H2O elimination. The latter process is part of a radical chain reaction at higher diol concentrations.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Royal Society of Chemistry  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Radicals in Water  
dc.subject
Vicinal Diols Reactivity  
dc.subject
Hydroxyl Radicals  
dc.subject.classification
Química Orgánica  
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Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Revisiting the reaction of hydroxyl radicals with vicinal diols in water  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2023-04-19T15:01:46Z  
dc.journal.volume
10  
dc.journal.number
5  
dc.journal.pagination
1102-1107  
dc.journal.pais
Reino Unido  
dc.journal.ciudad
Cambridge  
dc.description.fil
Fil: Jiang, Dong. University of Newcastle; Reino Unido  
dc.description.fil
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina  
dc.description.fil
Fil: Golding, Bernard T.. University of Newcastle; Reino Unido  
dc.description.fil
Fil: Ferreri, Carla. Consiglio Nazionale delle Ricerche; Italia  
dc.description.fil
Fil: Chatgilialoglu, Chryssostomos. Consiglio Nazionale delle Ricerche; Italia  
dc.journal.title
Organic & Biomolecular Chemistry  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2012/ob/c1ob06538f  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/C1OB06538F  

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