Artículo

Revisiting the reaction of hydroxyl radicals with vicinal diols in water

Jiang, Dong; Barata Vallejo, SebastianIcon ; Golding, Bernard T.; Ferreri, Carla; Chatgilialoglu, Chryssostomos
Fecha de publicación: 02/2012
Editorial: Royal Society of Chemistry
Revista: Organic & Biomolecular Chemistry
ISSN: 1477-0520
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The carbonyl products of the reactions of hydroxyl radicals with three vicinal diols (ethane-1,2-diol, propane-1,2-diol and butane-2,3-diol) have been identified and quantified. Hydroxyl radicals were produced by gamma-radiolysis of N2O-saturated aqueous solutions. The reactions result in the formation of alkoxyl radicals (15%) followed by beta-fragmentation, and alpha-hydroxyl alkyl radicals that undergo H2O elimination. The latter process is part of a radical chain reaction at higher diol concentrations.
Palabras clave: Radicals in Water , Vicinal Diols Reactivity , Hydroxyl Radicals
 
Archivos asociados
Thumbnail
 
Tamaño: 771.8Kb
Formato: PDF
.
Licencia
info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/194698
URL: https://pubs.rsc.org/en/content/articlelanding/2012/ob/c1ob06538f
DOI: http://dx.doi.org/10.1039/C1OB06538F
Colecciones
Articulos(SEDE CENTRAL)
Articulos de SEDE CENTRAL
Citación
Jiang, Dong; Barata Vallejo, Sebastian; Golding, Bernard T.; Ferreri, Carla; Chatgilialoglu, Chryssostomos; Revisiting the reaction of hydroxyl radicals with vicinal diols in water; Royal Society of Chemistry; Organic & Biomolecular Chemistry; 10; 5; 2-2012; 1102-1107
Compartir
Altmétricas