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dc.contributor.author
Cerna, Jorge  
dc.contributor.author
Bernès, Sylvain  
dc.contributor.author
Cañizo, Adriana Ines  
dc.contributor.author
Eyler, Gladys Nora  
dc.date.available
2022-08-02T01:05:25Z  
dc.date.issued
2009-10  
dc.identifier.citation
Cerna, Jorge; Bernès, Sylvain; Cañizo, Adriana Ines; Eyler, Gladys Nora; 3,3,6,6,9,9-Hexaethyl-1,2,4,5,7,8-hexa-oxacyclo-nonane at 296 K; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 65; 11; 10-2009; 562-564  
dc.identifier.issn
0108-2701  
dc.identifier.uri
http://hdl.handle.net/11336/163783  
dc.description.abstract
The title mol-ecule (diethyl ketone triperoxide, DEKTP), C 15H30O6, is a cyclic triperoxide closely related to triacetone triperoxide (TATP), one of the most unstable explosives known. However, the stability of DEKTP is ca 20-50 times greater than that of TATP. DEKTP crystallizes with two mol-ecules in the asymmetric unit, with virtually identical geometry. The cyclo-nonane core is stabilized in a twisted boat-chair conformation (approximate D3 symmetry), very close to that previously described for TATP. The explanation for the safe thermal behaviour of DEKTP compared with TATP should thus not be sought in the mol-ecular dimensions, but rather in the thermal decomposition kinetics.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Wiley Blackwell Publishing, Inc  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Hexaethyl  
dc.subject
hexaoxacyclononane  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
3,3,6,6,9,9-Hexaethyl-1,2,4,5,7,8-hexa-oxacyclo-nonane at 296 K  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2021-06-07T16:58:44Z  
dc.journal.volume
65  
dc.journal.number
11  
dc.journal.pagination
562-564  
dc.journal.pais
Alemania  
dc.journal.ciudad
Zurich  
dc.description.fil
Fil: Cerna, Jorge. Benemérita Universidad Autónoma de Puebla; México  
dc.description.fil
Fil: Bernès, Sylvain. Universidad Autónoma de Nuevo León; México  
dc.description.fil
Fil: Cañizo, Adriana Ines. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingeniería; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil; Argentina  
dc.description.fil
Fil: Eyler, Gladys Nora. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingeniería; Argentina  
dc.journal.title
Acta Crystallographica Section C-Crystal Structure Communications  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S0108270109039833  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1107/S0108270109039833  

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