Artículo

3,3,6,6,9,9-Hexaethyl-1,2,4,5,7,8-hexa-oxacyclo-nonane at 296 K

Cerna, Jorge; Bernès, Sylvain; Cañizo, Adriana InesIcon ; Eyler, Gladys Nora
Fecha de publicación: 10/2009
Editorial: Wiley Blackwell Publishing, Inc
Revista: Acta Crystallographica Section C-Crystal Structure Communications
ISSN: 0108-2701
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The title mol-ecule (diethyl ketone triperoxide, DEKTP), C 15H30O6, is a cyclic triperoxide closely related to triacetone triperoxide (TATP), one of the most unstable explosives known. However, the stability of DEKTP is ca 20-50 times greater than that of TATP. DEKTP crystallizes with two mol-ecules in the asymmetric unit, with virtually identical geometry. The cyclo-nonane core is stabilized in a twisted boat-chair conformation (approximate D3 symmetry), very close to that previously described for TATP. The explanation for the safe thermal behaviour of DEKTP compared with TATP should thus not be sought in the mol-ecular dimensions, but rather in the thermal decomposition kinetics.
Palabras clave: Hexaethyl , hexaoxacyclononane
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/163783
URL: http://scripts.iucr.org/cgi-bin/paper?S0108270109039833
DOI: http://dx.doi.org/10.1107/S0108270109039833
Colecciones
Articulos(CCT - TANDIL)
Articulos de CTRO CIENTIFICO TECNOLOGICO CONICET - TANDIL
Citación
Cerna, Jorge; Bernès, Sylvain; Cañizo, Adriana Ines; Eyler, Gladys Nora; 3,3,6,6,9,9-Hexaethyl-1,2,4,5,7,8-hexa-oxacyclo-nonane at 296 K; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 65; 11; 10-2009; 562-564
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