Artículo
Direct determination of parameters of activation of the unimolecular reaction of glutaraldehyde diperoxide by gas chromatography
Reguera, Mónica Beatriz; Galante, Nadia Soledad
; Varela, Noelia Melina; Profeta, Mariela Inés; Jorge, Maria Josefa; Jorge, Lilian Cristina; Romero, Jorge Marcelo; Jorge, Nelly Lidia
Fecha de publicación:
02/2020
Editorial:
Gupta Publications
Revista:
International Journal of Chemistry Studies
ISSN:
2581-348X
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Gas phase thermolysis reaction of glutaraldehyde acid diperoxide (3,6-dibutanoic -1,2,4,5-tetroxane,DPAG) was performed in an injection chamber of a gas chromatograph as a constant time thermal flow reactor, has been applied to obtain activation parameters.(DH#=13.07 ± 0.7 Kcal mol-1; DS#=-40,28 ± 0.4calmol-1 K-1; DG#=35.07 ± 0.7 Kcal mol-1) in the 453 – 553 K temperature range.
Palabras clave:
DPAG
,
THERMOLYSIS
,
KINETIC
,
GAS PHASE
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(CCT - NORDESTE)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - NORDESTE
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - NORDESTE
Citación
Reguera, Mónica Beatriz; Galante, Nadia Soledad; Varela, Noelia Melina; Profeta, Mariela Inés; Jorge, Maria Josefa; et al.; Direct determination of parameters of activation of the unimolecular reaction of glutaraldehyde diperoxide by gas chromatography; Gupta Publications; International Journal of Chemistry Studies; 4; 1; 2-2020; 52-55
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