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dc.contributor.author
Postigo, Jose Alberto
dc.date.available
2020-03-05T20:52:25Z
dc.date.issued
2018-12
dc.identifier.citation
Postigo, Jose Alberto; Electron Donor-Acceptor Complexes in Perfluoroalkylation Reactions; Wiley VCH Verlag; European Journal of Organic Chemistry; 2018; 46; 12-2018; 6391-6404
dc.identifier.issn
1434-193X
dc.identifier.uri
http://hdl.handle.net/11336/98882
dc.description.abstract
Electron-donor-acceptor complexes (EDA) can be established through halogen-bonding interactions between the N lone electron pair from organic bases (or N-/O-centered anions) and perfluoroalkyl iodides RF–I. These EDA complexes can be activated thermally or photochemically, and will be shown to be responsible for new C–RF bond formation reactions, bypassing the use of visible-light photocatalysts (either organic or organometallic) or harsh reaction conditions, thus simplifying reaction protocols, work-up and analysis. Through this strategy, diverse reaction types can be realized, such as atom transfer radical additions, homolytic aromatic substitutions, and multicomponent reactions.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley VCH Verlag
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
EDA COMPLEXES
dc.subject
PERFLUOROALKYLATION REACTIONS
dc.subject
PHOTOACTIVATION
dc.subject
PHOTOCHEMISTRY
dc.subject
VISIBLE-LIGHT ACTIVATION
dc.subject.classification
Química Orgánica
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Electron Donor-Acceptor Complexes in Perfluoroalkylation Reactions
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2020-03-05T15:00:17Z
dc.journal.volume
2018
dc.journal.number
46
dc.journal.pagination
6391-6404
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina
dc.journal.title
European Journal of Organic Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/ejoc.201801079
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201801079
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