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dc.contributor.author
Postigo, Jose Alberto  
dc.date.available
2020-03-05T20:52:25Z  
dc.date.issued
2018-12  
dc.identifier.citation
Postigo, Jose Alberto; Electron Donor-Acceptor Complexes in Perfluoroalkylation Reactions; Wiley VCH Verlag; European Journal of Organic Chemistry; 2018; 46; 12-2018; 6391-6404  
dc.identifier.issn
1434-193X  
dc.identifier.uri
http://hdl.handle.net/11336/98882  
dc.description.abstract
Electron-donor-acceptor complexes (EDA) can be established through halogen-bonding interactions between the N lone electron pair from organic bases (or N-/O-centered anions) and perfluoroalkyl iodides RF–I. These EDA complexes can be activated thermally or photochemically, and will be shown to be responsible for new C–RF bond formation reactions, bypassing the use of visible-light photocatalysts (either organic or organometallic) or harsh reaction conditions, thus simplifying reaction protocols, work-up and analysis. Through this strategy, diverse reaction types can be realized, such as atom transfer radical additions, homolytic aromatic substitutions, and multicomponent reactions.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Wiley VCH Verlag  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
EDA COMPLEXES  
dc.subject
PERFLUOROALKYLATION REACTIONS  
dc.subject
PHOTOACTIVATION  
dc.subject
PHOTOCHEMISTRY  
dc.subject
VISIBLE-LIGHT ACTIVATION  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Electron Donor-Acceptor Complexes in Perfluoroalkylation Reactions  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2020-03-05T15:00:17Z  
dc.journal.volume
2018  
dc.journal.number
46  
dc.journal.pagination
6391-6404  
dc.journal.pais
Alemania  
dc.journal.ciudad
Weinheim  
dc.description.fil
Fil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina  
dc.journal.title
European Journal of Organic Chemistry  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/ejoc.201801079  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201801079  

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