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Artículo

Metal-Modified Mesoporous Silicate (MCM-41) Material: Preparation, Characterization and Applications as an Adsorbent

Diez, Alejandra; Alvarez, MarianaIcon ; Volpe, María AliciaIcon
Fecha de publicación: 05/2015
Editorial: Sociedade Brasileira de Química
Revista: Journal Of The Brazilian Chemical Society
ISSN: 0103-5053
e-ISSN: 1678-4790
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:
Química Inorgánica y Nuclear

Resumen

Mesoporous silicate (MCM-41) materials, modified with CuII, FeIII or AlIII were prepared by a hydrothermal method and were characterized by nitrogen adsorption at 77 K, X-ray powder diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), temperature programmed reduction (TPR), adsorption of pyridine as monitored by Fourier transform infrared spectroscopy (FTIR) and n-butylamine titration. The degree of ordering of the mesoporous material was decreased by the presence of Cu, Fe, or Al. The added Fe or Cu gave rise to new acidic and oxidation-reduction sites, while Al resulted in new acidic sites. The hydrothermal stabilities of selected samples were studied as a function of temperature and pH. All the samples were stable in acidic and neutral media at temperatures from 303 to 363 K. Adsorption of phenol on MCM-41 at 303 K was strongly influenced by the pH and by the modification with Cu, Fe, or Al. Phenol adsorption was particularly strong at the Al-modified material at pH 3, apparently due to the acidic character of phenol.
Palabras clave: Mcm-41 , Metal Modification , Aqueous Stability , Phenol Adsorption
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/9808
URL: http://www.crossref.org/iPage?doi=10.5935%2F0103-5053.20150122
URL: http://ref.scielo.org/wmktt2
URL: http://jbcs.sbq.org.br/imagebank/pdf/v26n8a02.pdf
DOI: http://dx.doi.org/10.5935/0103-5053.20150122
Colecciones
Articulos(PLAPIQUI)
Articulos de PLANTA PILOTO DE INGENIERIA QUIMICA (I)
Citación
Diez, Alejandra; Alvarez, Mariana; Volpe, María Alicia; Metal-Modified Mesoporous Silicate (MCM-41) Material: Preparation, Characterization and Applications as an Adsorbent; Sociedade Brasileira de Química; Journal Of The Brazilian Chemical Society; 26; 8; 5-2015; 1542-1550
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