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dc.contributor.author
Garroni, Sebastiano
dc.contributor.author
Santoru, Antonio
dc.contributor.author
Cao, Hujun
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Dornheim, Martin
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Klassen, Thomas
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Milanese, Chiara
dc.contributor.author
Gennari, Fabiana Cristina
dc.contributor.author
Pistidda, Claudio
dc.date.available
2020-02-10T21:44:45Z
dc.date.issued
2018-04
dc.identifier.citation
Garroni, Sebastiano; Santoru, Antonio; Cao, Hujun; Dornheim, Martin; Klassen, Thomas; et al.; Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage; MDPI; Energies; 11; 5; 4-2018; 1-28
dc.identifier.issn
1996-1073
dc.identifier.uri
http://hdl.handle.net/11336/97141
dc.description.abstract
Hydrogen storage in the solid state represents one of the most attractive and challenging ways to supply hydrogen to a proton exchange membrane (PEM) fuel cell. Although in the last 15 years a large variety of material systems have been identified as possible candidates for storing hydrogen, further efforts have to be made in the development of systems which meet the strict targets of the Fuel Cells and Hydrogen Joint Undertaking (FCH JU) and U.S. Department of Energy (DOE). Recent projections indicate that a system possessing: (i) an ideal enthalpy in the range of 20-50 kJ/mol H2, to use the heat produced by PEM fuel cell for providing the energy necessary for desorption; (ii) a gravimetric hydrogen density of 5 wt. % H2 and (iii) fast sorption kinetics below 110 °C is strongly recommended. Among the known hydrogen storage materials, amide and imide-based mixtures represent the most promising class of compounds for on-board applications; however, some barriers still have to be overcome before considering this class of material mature for real applications. In this review, the most relevant progresses made in the recent years as well as the kinetic and thermodynamic properties, experimentally measured for the most promising systems, are reported and properly discussed.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
MDPI
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
HYDROGEN STORAGE MATERIALS
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METAL AMIDES
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THERMODYNAMICS AND KINETICS
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Ingeniería de los Materiales
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Ingeniería de los Materiales
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INGENIERÍAS Y TECNOLOGÍAS
dc.title
Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-10-15T17:30:09Z
dc.journal.volume
11
dc.journal.number
5
dc.journal.pagination
1-28
dc.journal.pais
Suiza
dc.journal.ciudad
Basilea
dc.description.fil
Fil: Garroni, Sebastiano. Universidad de Burgos; España
dc.description.fil
Fil: Santoru, Antonio. Helmholtz-Zentrum Geesthacht; Alemania
dc.description.fil
Fil: Cao, Hujun. Helmut Schmidt University; Alemania. Helmholtz-Zentrum Geesthacht; Alemania
dc.description.fil
Fil: Dornheim, Martin. Helmholtz-Zentrum Geesthacht; Alemania
dc.description.fil
Fil: Klassen, Thomas. Helmholtz-Zentrum Geesthacht; Alemania
dc.description.fil
Fil: Milanese, Chiara. University of Pavia; Italia
dc.description.fil
Fil: Gennari, Fabiana Cristina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
dc.description.fil
Fil: Pistidda, Claudio. Helmholtz-Zentrum Geesthacht; Alemania
dc.journal.title
Energies
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.3390/en11051027
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1073/11/5/1027
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