Artículo
Active nickel-based reduction of organic compounds
Fecha de publicación:
12/2003
Editorial:
Springer
Revista:
Russian Chemical Bulletin
ISSN:
1066-5285
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The reducing system NiCl2·2H2O-Li-arene cat (cat is catalyst) was proposed for use to reduce a wide range of organic compounds, including alkenes, alkynes, carbonyl compounds, imines, halogenated derivatives, sulfonates, aromatic compounds, hydrazines, azo and azoxy compounds, N-oxides, and nitrones. The degree of reduction can be controlled for some substrates. Deuterium can be incorporated in the reaction products using nickel chloride deuteriohydrate. Nitrones, N-alkoxyamides, and acyl azides are also reduced with the Li-arenecat system containing no nickel salt.
Palabras clave:
ACTIVE METALS
,
CATALYSIS BY ARENES
,
ORGANIC COMPOUNDS
,
REDUCTION
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(INQUISUR)
Articulos de INST.DE QUIMICA DEL SUR
Articulos de INST.DE QUIMICA DEL SUR
Citación
Alonso, F.; Radivoy, Gabriel Eduardo; Yus, M.; Active nickel-based reduction of organic compounds; Springer; Russian Chemical Bulletin; 52; 12; 12-2003; 2563-2576
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