Capítulo de Libro

HNO: redox chemistry and interactions with small inorganic molecules

Título del libro: The Chemistry and Biology of Nitroxyl (HNO)

Hamer, MarianaIcon ; Morales Vasquez, Miguel AngelIcon ; Doctorovich, FabioIcon
Fecha de publicación: 2017
Editorial: Elsevier
ISBN: 9780128009345
Idioma: Inglés
Clasificación temática:

Resumen

This chapter deals with the reactivity of nitroxyl in its different spin states (singlet/protonated, triplet/deprotonated) toward itself and other small molecules. Fast dimerization of HNO/NO− produces N2O as an end product. Nitroxyl is oxidized by reaction with O2 producing NO or peroxynitrite, depending on its spin state. The relationship of NO with HNO regarding interactions between these species and their possible interconversion pathways will be also discussed. Finally, the reaction between HNO and H2S will be mentioned.
Palabras clave: NITROXYLO , REDOX , REACTIVITY , SPIN STATE
 
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Tamaño: 184.4Kb
Formato: PDF
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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/95915
URL: https://www.sciencedirect.com/science/article/pii/B9780128009345000013
DOI: https://doi.org/10.1016/B978-0-12-800934-5.00001-3
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Capítulos de libros de INST.DE QUIMICA Y FISICO-QUIMICA BIOLOGICAS "PROF. ALEJANDRO C. PALADINI"
Citación
Hamer, Mariana; Morales Vasquez, Miguel Angel; Doctorovich, Fabio; HNO: redox chemistry and interactions with small inorganic molecules; Elsevier; 2017; 1-9
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