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dc.contributor.author
Veronica, Martino
dc.contributor.author
Jimenez, Alfonso
dc.contributor.author
Ruseckaite, Roxana Alejandra
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dc.contributor.author
Luc, Averous
dc.date.available
2016-12-15T21:39:17Z
dc.date.issued
2010-07-15
dc.identifier.citation
Veronica, Martino; Jimenez, Alfonso; Ruseckaite, Roxana Alejandra; Luc, Averous; Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates; Wiley; Polymers For Advanced Technologies; 22; 12; 15-7-2010; 2206-2213
dc.identifier.issn
1099-1581
dc.identifier.uri
http://hdl.handle.net/11336/9541
dc.description.abstract
The use of nano-biocomposites based on plasticized poly(lactic acid) (PLA) has been proposed as a way to improve the polymer ductility and to expand PLA applications window. Novative nano-biocomposites were elaborated with PLA
plasticized by polyadipates (15 wt%) with different molar masses (from 1500 to 2500 Da), with 2.1 wt% of an organo-modified montmorillonite (O-MMT). These materials showed enhanced ductility and barrier properties. The clay was swelled in liquid polyadipates prior to their blending with PLA to facilitate chains intercalation and nanofiller exfoliation during melt-blending. In certain processing conditions, quite homogenous and exfoliated structures were obtained, as shown by X-ray diffraction (XRD) and transmission electronic microscopy (TEM) results. Irrespective of the average molar mass of the polyadipate, the clay addition induced a reduction in around 25% in oxygen transmission rate (OTR) without an important detriment in tensile properties. Nano-biocomposites prepared with higher molar masses polyadipates showed the highest thermal stability as well as the lowest OTR, resulting in very promising and novative materials for different applications such as soft packaging.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Poly(Lactic Acid)
dc.subject
Montmorillonite
dc.subject
Oxygen Transmission
dc.subject
Ductility
dc.subject
Polyadipates
dc.subject.classification
Compuestos
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dc.subject.classification
Ingeniería de los Materiales
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dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
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dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica
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dc.subject.classification
Ciencias Químicas
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dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
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dc.title
Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2016-10-26T21:19:38Z
dc.journal.volume
22
dc.journal.number
12
dc.journal.pagination
2206-2213
dc.journal.pais
Estados Unidos
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dc.description.fil
Fil: Veronica, Martino. Universite de Strasbourg; Francia
dc.description.fil
Fil: Jimenez, Alfonso. Universidad de Alicante. Departamento de Quiâmica Orgánica; España
dc.description.fil
Fil: Ruseckaite, Roxana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
dc.description.fil
Fil: Luc, Averous. Universite de Strasbourg; Francia
dc.journal.title
Polymers For Advanced Technologies
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/issn/1099-1581
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pat.1747/full
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/pat.1747
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