Artículo

Room-Temperature and Transition-Metal-Free Mizoroki Heck-type Reaction. Synthesis of E-Stilbenes by Photoinduced C-H Functionalization

Guastavino, Javier FernandoIcon ; Buden, Maria EugeniaIcon ; Rossi, Roberto ArturoIcon
Fecha de publicación: 01/2014
Editorial: American Chemical Society
Revista: Journal Of Organic Chemistry
ISSN: 0022-3263
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

We report a conceptually different approach toward E-stilbene syntheses by photoinduced direct C-H arylation of alkenes at rt without the addition of transition metals, with a broad range of aryl halides, including ArI, ArBr, and even ArCl. This is the first time that this reaction has been produced without extra solvent but with 18-crown-6 ether and t-BuOK in only 15 min of reaction.
Palabras clave: Alkenes , Arylation , Photochemistry , Stilbene
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/9270
DOI: http://dx.doi.org/10.1021/jo501474w
URL: http://pubs.acs.org/doi/abs/10.1021/jo501474w
Colecciones
Articulos(INTEC)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Guastavino, Javier Fernando; Buden, Maria Eugenia; Rossi, Roberto Arturo; Room-Temperature and Transition-Metal-Free Mizoroki Heck-type Reaction. Synthesis of E-Stilbenes by Photoinduced C-H Functionalization; American Chemical Society; Journal Of Organic Chemistry; 79; 1-2014; 9104-9111
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