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Artículo

Highly-organized stacked multilayers: Via layer-by-layer assembly of lipid-like surfactants and polyelectrolytes. Stratified supramolecular structures for (bio)electrochemical nanoarchitectonics

Cortez, María LorenaIcon ; Lorenzo, AgustinIcon ; Marmisollé, Waldemar AlejandroIcon ; Von Bilderling, CatalinaIcon ; Maza, Eliana MaríaIcon ; Pietrasanta, LiaIcon ; Battaglini, FernandoIcon ; Ceolin, Marcelo RaulIcon ; Azzaroni, OmarIcon
Fecha de publicación: 02/2018
Editorial: Royal Society of Chemistry
Revista: Soft Matter
ISSN: 1744-683X
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:
Físico-Química, Ciencia de los Polímeros, Electroquímica

Resumen

Supramolecular self-assembly is of paramount importance for the development of novel functional materials with molecular-level feature control. In particular, the interest in creating well-defined stratified multilayers through simple methods using readily available building blocks is motivated by a multitude of research activities in the field of "nanoarchitectonics" as well as evolving technological applications. Herein, we report on the facile preparation and application of highly organized stacked multilayers via layer-by-layer assembly of lipid-like surfactants and polyelectrolytes. Polyelectrolyte multilayers with high degree of stratification of the internal structure were constructed through consecutive assembly of polyallylamine and dodecyl phosphate, a lipid-like surfactant that act as a structure-directing agent. We show that multilayers form well-defined lamellar hydrophilic/hydrophobic domains oriented parallel to the substrate. More important, X-ray reflectivity characterization conclusively revealed the presence of Bragg peaks up to fourth order, evidencing the highly stratified structure of the multilayer. Additionally, hydrophobic lamellar domains were used as hosts for ferrocene in order to create an electrochemically active film displaying spatially-addressed redox units. Stacked multilayers were then assembled integrating redox-tagged polyallylamine and glucose oxidase into the stratified hydrophilic domains. Bioelectrocatalysis and "redox wiring" in the presence of glucose was demonstrated to occur inside the stratified multilayer.
Palabras clave: Lipid-like surfactants , Nanoarchitectonics , Stratified multilayers , Polyelectrolytes
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/88740
URL: https://pubs.rsc.org/en/content/articlelanding/2018/SM/C8SM00052B#!divAbstract
DOI: http://dx.doi.org/10.1039/C8SM00052B
Colecciones
Articulos(IFIBA)
Articulos de INST.DE FISICA DE BUENOS AIRES
Articulos(INIFTA)
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Articulos(INQUIMAE)
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Citación
Cortez, María Lorena; Lorenzo, Agustin; Marmisollé, Waldemar Alejandro; Von Bilderling, Catalina; Maza, Eliana María; et al.; Highly-organized stacked multilayers: Via layer-by-layer assembly of lipid-like surfactants and polyelectrolytes. Stratified supramolecular structures for (bio)electrochemical nanoarchitectonics; Royal Society of Chemistry; Soft Matter; 14; 10; 2-2018; 1939-1952
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