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dc.contributor.author
Buden, Maria Eugenia  
dc.contributor.author
Guastavino, Javier Fernando  
dc.contributor.author
Rossi, Roberto Arturo  
dc.date.available
2016-12-05T18:18:37Z  
dc.date.issued
2013-03  
dc.identifier.citation
Buden, Maria Eugenia; Guastavino, Javier Fernando; Rossi, Roberto Arturo; Room-Temperature Photoinduced Direct C-H-Arylation via Base-Promoted Homolytic Aromatic Substitution; American Chemical Society; Organic Letters; 15; 6; 3-2013; 1174-1176  
dc.identifier.issn
1523-7060  
dc.identifier.uri
http://hdl.handle.net/11336/8791  
dc.description.abstract
Conceptually different approach toward biaryl syntheses by photoinduced direct CH arylation of benzene and thiophene in the presence of t-BuOK is reported. The reaction proceeds through photo- and base-promoted homolytic aromatic substitution. The o-, m- and p- substituted ArI, as well as the electron-donating and electron-withdrawing nature of the substituents were found be good to excellent substrates. Heteroaryl, ArBr, ArCl and double CH arylation were successfully achieved.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
American Chemical Society  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Biaryls  
dc.subject
C-H Arylation  
dc.subject
Has  
dc.subject
Photochemistry  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Room-Temperature Photoinduced Direct C-H-Arylation via Base-Promoted Homolytic Aromatic Substitution  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2016-12-02T15:59:49Z  
dc.journal.volume
15  
dc.journal.number
6  
dc.journal.pagination
1174-1176  
dc.journal.pais
Estados Unidos  
dc.journal.ciudad
Washington  
dc.description.fil
Fil: Buden, Maria Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; Argentina  
dc.description.fil
Fil: Guastavino, Javier Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones en Físicoquímica de Córdoba; Argentina  
dc.description.fil
Fil: Rossi, Roberto Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; Argentina  
dc.journal.title
Organic Letters  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/ol3034687  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ol3034687  

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