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dc.contributor.author
Riveira, Martín Jorge  
dc.contributor.author
Sarotti, Ariel Marcelo  
dc.date.available
2019-10-24T21:12:55Z  
dc.date.issued
2018-03  
dc.identifier.citation
Riveira, Martín Jorge; Sarotti, Ariel Marcelo; NMR and experimental reinvestigation of the condensation reaction between γ-methylene-α,β-unsaturated aldehydes and propargyl aldehydes; Royal Society of Chemistry; Organic & Biomolecular Chemistry; 16; 9; 3-2018; 1442-1447  
dc.identifier.issn
1477-0520  
dc.identifier.uri
http://hdl.handle.net/11336/87281  
dc.description.abstract
The condensation reaction between a γ-methylene-α,β-unsaturated aldehyde and phenylpropargyl aldehyde was revisited and, guided by extensive DFT calculations of NMR shifts, was found to afford a deconjugative aldol condensation product. In this manner, a simple protocol for the preparation of valuable cross-conjugated oxatrienes was uncovered.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Royal Society of Chemistry  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
UNSATURATED ALDEHYDES  
dc.subject
ALDOL CONDENSATION  
dc.subject
ORGANOCATALYSIS  
dc.subject
COMPUTATIONAL CHEMISTRY  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
NMR and experimental reinvestigation of the condensation reaction between γ-methylene-α,β-unsaturated aldehydes and propargyl aldehydes  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2019-10-16T19:17:04Z  
dc.journal.volume
16  
dc.journal.number
9  
dc.journal.pagination
1442-1447  
dc.journal.pais
Reino Unido  
dc.description.fil
Fil: Riveira, Martín Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina  
dc.description.fil
Fil: Sarotti, Ariel Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina  
dc.journal.title
Organic & Biomolecular Chemistry  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/C7OB03110F  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2018/OB/C7OB03110F  

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