DFT study of hydrogen adsorption on Ni/graphene

Abstract

DFT calculations with the GGA-PBE exchange correlation functional were used to study H 2 adsorption on a Ni(1 1 1) surface, isolated Ni 13 cluster, and graphene-supported Ni 13 . In comparison with Ni(1 1 1), hydrogen adsorption shows to be more stable on isolated Ni 13 and graphene-supported Ni 13 . In the graphene-supported Ni 13 , pseudo charge density difference calculations showed accumulation of charge density around the Ni-graphene interfacial region. Dissociative H 2 adsorption on Ni(1 1 1) and isolated Ni 13 appears to be a non-activated process, whereas an activation barrier is observed on the graphene-supported Ni 13 . Additionally, the effect of pre-adsorbed hydrogen in H 2 adsorption in the mentioned systems was studied showing that it stabilizes the final state of adsorbed H and decreases the activation barrier.