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dc.contributor.author
Fernandez, Ariel
dc.date.available
2019-10-11T20:02:11Z
dc.date.issued
2017-06-12
dc.identifier.citation
Fernandez, Ariel; Dielectric response of frustrated water down to a single-molecule contribution; Wiley VCH Verlag; Annalen Der Physik; 529; 6; 12-6-2017; 1-5
dc.identifier.issn
0003-3804
dc.identifier.uri
http://hdl.handle.net/11336/85799
dc.description.abstract
A theory of dielectric response of water under nanoscale confinement was long overdue. This work addresses the problem by establishing a relation between dielectric response and hydrogen-bond frustration subsumed in a non-Debye polarization term. The results hold down to the single-molecule contribution and are validated vis-à-vis experimental measurements on a system where dielectric modulation entails removal of a single water molecule. The frustrated dielectric response down to molecular scales is assessed by contrasting two enantiomeric ligands in association with the same protein, with the complexes differing in the removal of a single interfacial water molecule.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley VCH Verlag
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
DEBYE POLARIZATION
dc.subject
DEHYDRON
dc.subject
DIELECTRIC RESPONSE
dc.subject
FRUSTRATED WATER
dc.subject
HYDROGEN BOND
dc.subject
INTERFACIAL WATER
dc.subject
NANO-SCALE CONFINEMENT
dc.subject.classification
Matemática Aplicada
dc.subject.classification
Matemáticas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Dielectric response of frustrated water down to a single-molecule contribution
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-10-04T17:10:54Z
dc.journal.volume
529
dc.journal.number
6
dc.journal.pagination
1-5
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Fernandez, Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Saavedra 15. Instituto Argentino de Matemática Alberto Calderón; Argentina
dc.journal.title
Annalen Der Physik
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/andp.201600373
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/andp.201600373
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