Artículo

Solubility of two stable iminium salts in 12 polar solvents

Grande, Maria del Carmen; Barrero, Carmen Raquel; Marschoff, Carlos Miguel; Rodriguez, Juan BautistaIcon ; Gros, Eduardo G.
Fecha de publicación: 11/2002
Editorial: American Chemical Society
Revista: Journal of Chemical and Engineering Data
ISSN: 0021-9568
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated.
Palabras clave: Properties of iminium salts , Solubility data , Thermodynamic quantities
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/85792
URL: https://pubs.acs.org/doi/abs/10.1021/je010263o
DOI: https://doi.org/10.1021/je010263o
Colecciones
Articulos(UMYMFOR)
Articulos de UNID.MICROANAL.Y MET.FISICOS EN QUIM.ORG.(I)
Citación
Grande, Maria del Carmen; Barrero, Carmen Raquel; Marschoff, Carlos Miguel; Rodriguez, Juan Bautista; Gros, Eduardo G.; Solubility of two stable iminium salts in 12 polar solvents; American Chemical Society; Journal of Chemical and Engineering Data; 47; 6; 11-2002; 1337-1338
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