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dc.contributor.author
Fracaroli, Alejandro Matías
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dc.contributor.author
Hoyos, Maria Rita Micaela
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dc.date.available
2019-10-09T13:33:45Z
dc.date.issued
2018-10
dc.identifier.citation
Fracaroli, Alejandro Matías; Hoyos, Maria Rita Micaela; Supramolecular chemistry in solid state materials such as metal-organic frameworks; Science From Israel-division Of Laser Pages Publ Ltd; Israel Journal Of Chemistry; 58; 9; 10-2018; 1102-1111
dc.identifier.issn
0021-2148
dc.identifier.uri
http://hdl.handle.net/11336/85433
dc.description.abstract
Supramolecular chemistry has enriched the scientific research for more than fifty years reaching one of its summits in 2016, when the Chemistry Nobel Prize was awarded for the design and synthesis of molecular machines, in which host-guest chemistry plays a fundamental role. Recently, the groups of Omar Yaghi and Fraser Stoddart, among others, have demonstrated that this chemistry can be extended to the pores of metal-organic frameworks (MOFs). This heterogenization of supramolecular chemistry can be achieved through the incorporation of macrocycles to the organic struts of these highly porous and crystalline materials. Throughout this short review we summarize interesting examples of selective recognition by naturally occurring and synthetic macrocycles in solution and solid state; and later we survey important milestones to achieve specific recognition sites and develop host-guest chemistry at the pores of MOFs.This summary contains examples of different synthetic strategies to incorporate macrocycles to solid state materials, and in particular, to prepare supramolecular MOFs with particular properties and related applications. Specifically, the revised research includes the incorporation of both naturally occurring and synthetic macrocycles to solid state materials such as polymers, metal nanoparticles, etc., as prelude of the solid phase recognition studied in MOFs. An important number of the contributions presented here feature porous solids with smooth access to the host´s cavity incorporated in the pores, allowing specific recognition of guest molecules. This smooth access to those active recognition sites in materials with extremely high surface area such as MOFs, open the possibility to develop the next generation of frontier materials with application in fields such as selective capture of water toxins and heterogeneous catalysis, among others.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Science From Israel-division Of Laser Pages Publ Ltd
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
MACROCYCLES
dc.subject
METAL-ORGANIC FRAMEWORKS (MOFS)
dc.subject
SOLID PHASE RECOGNITION PROCESS
dc.subject
SUPRAMOLECULAR CHEMISTRY
dc.subject.classification
Otras Ciencias Químicas
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dc.subject.classification
Ciencias Químicas
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dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
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dc.title
Supramolecular chemistry in solid state materials such as metal-organic frameworks
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-09-30T18:25:52Z
dc.identifier.eissn
1869-5868
dc.journal.volume
58
dc.journal.number
9
dc.journal.pagination
1102-1111
dc.journal.pais
Israel
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dc.journal.ciudad
Jerusalem
dc.description.fil
Fil: Fracaroli, Alejandro Matías. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
dc.description.fil
Fil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
dc.journal.title
Israel Journal Of Chemistry
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/ijch.201800114
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1002/ijch.201800114
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