Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate

Abstract

In the title compound, C14H14N2OS 2, the furan ring exhibits rotational disorder over two orientations, with an occupancy ratio of 0.508 (7):0.492 (7). The furan and phenyl rings form dihedral angles of 8.2 (6) (major occupancy component), 14.8 (6) (minor occupancy component) and 73.65 (9)°, respectively, with the central residue (C4N2S2), indicating a twisted conformation for the molecule. The methyl group and the thione S atom are syn and the conformation about the imine bond is E. In the crystal, C - H⋯π interactions involving the phenyl ring are observed.