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dc.contributor.author
Brunetti, Veronica  
dc.contributor.author
Lopez Teijelo, Manuel  
dc.date.available
2019-08-30T18:28:42Z  
dc.date.issued
2008-02  
dc.identifier.citation
Brunetti, Veronica; Lopez Teijelo, Manuel; Oxide/hydroxide films on tin. II: Characterization of the anodic growth in alkaline solutions; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 613; 1; 2-2008; 16-22  
dc.identifier.issn
0022-0728  
dc.identifier.uri
http://hdl.handle.net/11336/82625  
dc.description.abstract
The anodic growth of oxide/hydroxide films formed on tin in borate solutions (pH 8.9) has been studied. At potentials more positive than -0.2 V (SHE), oxide film growth occurs by an activation-controlled ionic condition under the influence of a high electric field across the film according to an exponential law as on valve metals. Optical properties of the anodic oxide films have been obtained by "in situ" ellipsometry. Tin oxide/hydroxide films are practically transparent and highly hydrated. Electrical properties of tin oxide layers have been obtained by electrochemical impedance spectroscopy. Impedance spectra are explained in terms of a simple physical model assuming that oxide layer behaves as an inhomogeneous single-layer film.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science Sa  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Electrochemical Impedance Spectroscopy  
dc.subject
Ellipsometry  
dc.subject
High-Field Growth  
dc.subject
Oxide/Hydroxide Layers  
dc.subject
Tin Oxide  
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Oxide/hydroxide films on tin. II: Characterization of the anodic growth in alkaline solutions  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2019-05-06T14:16:48Z  
dc.identifier.eissn
1572-6657  
dc.journal.volume
613  
dc.journal.number
1  
dc.journal.pagination
16-22  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Brunetti, Veronica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina  
dc.description.fil
Fil: Lopez Teijelo, Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina  
dc.journal.title
Journal of Electroanalytical Chemistry  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022072807004512  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.jelechem.2007.10.001  

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