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dc.contributor.author Bidabehere, Claudia María
dc.contributor.author Sedran, Ulises Anselmo
dc.date.available 2019-06-19T17:41:25Z
dc.date.issued 2001-04
dc.identifier.citation Bidabehere, Claudia María; Sedran, Ulises Anselmo; Simultaneous diffusion, adsorption, and reaction in fluid catalytic cracking catalysts; American Chemical Society; Industrial & Engineering Chemical Research; 40; 2; 4-2001; 530-535
dc.identifier.issn 0888-5885
dc.identifier.uri http://hdl.handle.net/11336/78549
dc.description.abstract Simultaneous diffusion, adsorption, and reaction that take place inside the zeolitic component of equilibrium commercial fluid catalytic cracking (FCC) catalysts were described by means of heterogeneous models. n-Hexadecane was used as a test reactant at high temperatures (440-550°C) over two different equilibrium catalysts under very short contact times up to 10 s in a Riser Simulator reactor. The system's parameters were obtained by fitting the model to the reactant's gas-phase concentration versus reaction time data. When zeolite intracrystalline diffusion was first assumed as the controlling mechanism for mass transfer, its energy of activation resulted close to the heat of adsorption, suggesting that diffusion in the zeolite micropores could be indeed controlling. The solution under this new approach led to the obtention of parameters that were consistent with the existence of strong diffusion limitations for the reaction and with lower activity in the low unit cell size catalyst. Diffusion, which would be a nonactivated process, had coefficients that were essentially the same in both catalysts, while the energies of activation of the reaction were different and reflected the higher relative importance of the mechanism of monomolecular cracking in the more dealuminated catalyst. The need for a careful assessment of adsorption parameters in FCC catalysts was confirmed by the fact that their magnitudes change significantly as a function of temperature, with adsorption being somewhat stronger on the higher unit cell size catalyst in the temperature range of interest for FCC. The method employed proved to be adequate and sensitive for the quantification of these issues, which are important in reactor design and simulation and catalyst evaluation procedures.
dc.format application/pdf
dc.language.iso eng
dc.publisher American Chemical Society
dc.rights info:eu-repo/semantics/restrictedAccess
dc.rights.uri https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject Diffusion
dc.subject Adsorption
dc.subject FCC
dc.subject Hydrocarbons
dc.subject.classification Otras Ingeniería Química
dc.subject.classification Ingeniería Química
dc.subject.classification INGENIERÍAS Y TECNOLOGÍAS
dc.title Simultaneous diffusion, adsorption, and reaction in fluid catalytic cracking catalysts
dc.type info:eu-repo/semantics/article
dc.type info:ar-repo/semantics/artículo
dc.type info:eu-repo/semantics/publishedVersion
dc.date.updated 2019-06-19T12:18:04Z
dc.journal.volume 40
dc.journal.number 2
dc.journal.pagination 530-535
dc.journal.pais Estados Unidos
dc.journal.ciudad Washington
dc.description.fil Fil: Bidabehere, Claudia María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
dc.description.fil Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.journal.title Industrial & Engineering Chemical Research
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/ie990803z
dc.conicet.fuente individual


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    Articulos de INST.DE INVEST.EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"

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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)