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dc.contributor.author
Tarutani, Naoki
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Tokudome, Yasuaki
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Jobbagy, Matias
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Viva, Federico Andrés
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Soler Illia, Galo Juan de Avila Arturo
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Takahashi, Masahide
dc.date.available
2019-06-11T17:05:50Z
dc.date.issued
2016-12
dc.identifier.citation
Tarutani, Naoki; Tokudome, Yasuaki; Jobbagy, Matias; Viva, Federico Andrés; Soler Illia, Galo Juan de Avila Arturo; et al.; Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials; American Chemical Society; Chemistry Of Materials; 28; 16; 12-2016; 5606-5610
dc.identifier.issn
0897-4756
dc.identifier.uri
http://hdl.handle.net/11336/77953
dc.description.abstract
A study demonstrated a simple synthesis approach toward single-nanometer-sized crystals that work as nanobuilding blocks (NBBs) to form a great variety of mesoporous hydroxides and derived phases. The nanocrystals with diverse chemical compositions low-valence metal hydroxides, α-M(OH)2 (M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)), and other (hydr)oxides composed of Al(III), Cr(III), Fe(III), Zr(IV), and Sn(IV)) were prepared in an aqueous ethanol solution. The nanocrystal formation was achieved by inducing a high supersaturation via the epoxidemediated alkalinization in a concentrated metal salt solution. A variety of carboxylic acids were used as growth controlling agents, permitting to finely control the size of low-valence metal hydroxide nanocrystals and to attain high stability against aggregation.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Metal Oxides
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Layered Double Hydroxide
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Mesoporous Material
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Supercapacitor
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Otras Ciencias Químicas
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-06-10T20:35:25Z
dc.journal.volume
28
dc.journal.number
16
dc.journal.pagination
5606-5610
dc.journal.pais
Estados Unidos
dc.journal.ciudad
Washington
dc.description.fil
Fil: Tarutani, Naoki. Osaka Prefecture University; Japón
dc.description.fil
Fil: Tokudome, Yasuaki. Osaka Prefecture University; Japón
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Fil: Jobbagy, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
dc.description.fil
Fil: Viva, Federico Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
dc.description.fil
Fil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
dc.description.fil
Fil: Takahashi, Masahide. Osaka Prefecture University; Japón
dc.journal.title
Chemistry Of Materials
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.6b02510
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1021/acs.chemmater.6b02510
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