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dc.contributor.author
Grosse, Constantino
dc.date.available
2019-06-10T19:51:45Z
dc.date.issued
2009-08
dc.identifier.citation
Grosse, Constantino; Generalization of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to electrolyte solutions with different ion valences; American Chemical Society; Journal of Physical Chemistry B; 113; 8-2009; 11201-11215
dc.identifier.issn
1520-6106
dc.identifier.uri
http://hdl.handle.net/11336/77884
dc.description.abstract
The classic Shilov-Dukhin theory of the low frequency dielectric dispersion of colloidal suspensions in binary electrolyte solutions was developed for symmetric electrolytes: equal counterion and co-ion valences. A rigorous generalization of this theory to asymmetric electrolytes, such that the valence of counterions is double or half the valence of co-ions, is presented. This generalization is possible because analytical solutions of the intervening integrals exist for these two particular cases but do not exist in the general case of different counterion and co-ion valences, a result apparently overlooked or ignored in the past.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Colloids
dc.subject
Lfdd
dc.subject
Dielectric Dispersion
dc.subject
Theory
dc.subject.classification
Astronomía
dc.subject.classification
Ciencias Físicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Generalization of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to electrolyte solutions with different ion valences
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-06-10T13:41:56Z
dc.journal.volume
113
dc.journal.pagination
11201-11215
dc.journal.pais
Estados Unidos
dc.journal.ciudad
New York
dc.description.fil
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina
dc.journal.title
Journal of Physical Chemistry B
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1021/jp904742v
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jp904742v
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