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dc.contributor.author
Coronel, Leandro
dc.contributor.author
Múnera Agudelo, John Fernando
dc.contributor.author
Lombardo, Eduardo Agustin
dc.contributor.author
Cornaglia, Laura Maria
dc.date.available
2019-04-08T20:06:51Z
dc.date.issued
2011-06
dc.identifier.citation
Coronel, Leandro; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies; Elsevier Science; Applied Catalysis A: General; 400; 1-2; 6-2011; 185-194
dc.identifier.issn
0926-860X
dc.identifier.uri
http://hdl.handle.net/11336/73490
dc.description.abstract
A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O 3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function of the sweep gas flow rate. The correlation between methane conversion enhancement and hydrogen recovery confirmed that a good prediction was obtained with this model. The performance of two reactor configurations (membrane reactor and conventional fixed-bed reactor) and both co-current and counter-current flow modes were compared. The effect of various operating variables such as permeation area, sweep gas flow rate and feed composition upon conversion, product compositions and hydrogen recovery were analyzed.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
Kinetic Equations
dc.subject
Membrane Reactor
dc.subject
Rh Catalysts
dc.subject.classification
Otras Ciencias Químicas
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2019-04-01T16:14:44Z
dc.journal.volume
400
dc.journal.number
1-2
dc.journal.pagination
185-194
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Coronel, Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.journal.title
Applied Catalysis A: General
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2011.04.030
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X11002493


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