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dc.contributor.author Coronel, Leandro
dc.contributor.author Múnera Agudelo, John Fernando
dc.contributor.author Lombardo, Eduardo Agustin
dc.contributor.author Cornaglia, Laura Maria
dc.date.available 2019-04-08T20:06:51Z
dc.date.issued 2011-06
dc.identifier.citation Coronel, Leandro; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies; Elsevier Science; Applied Catalysis A: General; 400; 1-2; 6-2011; 185-194
dc.identifier.issn 0926-860X
dc.identifier.uri http://hdl.handle.net/11336/73490
dc.description.abstract A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O 3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function of the sweep gas flow rate. The correlation between methane conversion enhancement and hydrogen recovery confirmed that a good prediction was obtained with this model. The performance of two reactor configurations (membrane reactor and conventional fixed-bed reactor) and both co-current and counter-current flow modes were compared. The effect of various operating variables such as permeation area, sweep gas flow rate and feed composition upon conversion, product compositions and hydrogen recovery were analyzed.
dc.format application/pdf
dc.language.iso eng
dc.publisher Elsevier Science
dc.rights info:eu-repo/semantics/restrictedAccess
dc.rights.uri https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject KINETIC EQUATIONS
dc.subject MEMBRANE REACTOR
dc.subject RH CATALYSTS
dc.subject.classification Otras Ciencias Químicas
dc.subject.classification Ciencias Químicas
dc.subject.classification CIENCIAS NATURALES Y EXACTAS
dc.title Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
dc.type info:eu-repo/semantics/article
dc.type info:ar-repo/semantics/artículo
dc.type info:eu-repo/semantics/publishedVersion
dc.date.updated 2019-04-01T16:14:44Z
dc.journal.volume 400
dc.journal.number 1-2
dc.journal.pagination 185-194
dc.journal.pais Países Bajos
dc.journal.ciudad Amsterdam
dc.description.fil Fil: Coronel, Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.journal.title Applied Catalysis A: General
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2011.04.030
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X11002493
dc.conicet.fuente unificacion


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    Articulos de INST.DE INVEST.EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"

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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Atribución-NoComercial-SinDerivadas 2.5 Argentina (CC BY-NC-ND 2.5 AR)