Artículo

Charge regulation in redox active monolayers embedded in proton exchanger surfaces

Ricci, A.M.; Tagliazucchi, Mario EugenioIcon ; Calvo, Ernesto JulioIcon
Fecha de publicación: 07/2012
Editorial: Royal Society of Chemistry
Revista: Physical Chemistry Chemical Physics
ISSN: 1463-9076
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Experimental evidence of the variation in redox potential of osmium pyridine complexes tethered to a Au surface by thiol or diazonium chemistry at different ionic concentration and electrolyte pH is described. The interplay between the charged redox and acid groups is described by a charge regulation model based on PM-IRRAS spectroscopic evidence on the different degrees of surface protonation.
Palabras clave: Self Assembled Monolayer , Charge Regulation , Osmium Complex , Surface Potential
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/72395
URL: https://pubs.rsc.org/en/Content/ArticleLanding/2012/CP/c2cp40695k#!divAbstract
DOI: http://dx.doi.org/10.1039/C2CP40695K
Colecciones
Articulos(INQUIMAE)
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Citación
Ricci, A.M.; Tagliazucchi, Mario Eugenio; Calvo, Ernesto Julio; Charge regulation in redox active monolayers embedded in proton exchanger surfaces; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 14; 28; 7-2012; 9988-9995
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