Artículo

Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands

Martínez, Miguel A.; De Jiménez, María C.L.; Castellano, Eduardo E.; Piro, Oscar EnriqueIcon ; Aymonino, Pedro JoseIcon
Fecha de publicación: 06/2003
Editorial: Taylor & Francis Ltd
Revista: Journal of Coordination Chemistry
ISSN: 0095-8972
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The reaction of lapachol, 2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphtoquinone, C15H 14O3, with zinc acetate, in ethanol, produces a chelate formula Zn(C15H13O3)2(C 2H6O)2, whose structure has been determined by single crystal X-ray diffraction. It pertains to the triclinic system, space group P 1̄ (No. 2), a = 8.2380(3) Å, b = 9.4900(2) Å, c = 11.0110(4) Å, α = 112.536(2)°, β = 91.204(2)°, γ = 92.664(2)°, Z = 1. Some spectroscopic and chemical properties of the complex are also reported.
Palabras clave: Ethanol , Lapacholate , Properties , Structure , Zn(Ii) Complex
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
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URI: http://hdl.handle.net/11336/72355
DOI: https://doi.org/10.1080/0095897031000113959
URL: https://www.tandfonline.com/doi/abs/10.1080/0095897031000113959
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Articulos(IFLP)
Articulos de INST.DE FISICA LA PLATA
Citación
Martínez, Miguel A.; De Jiménez, María C.L.; Castellano, Eduardo E.; Piro, Oscar Enrique; Aymonino, Pedro Jose; Synthesis, structure and properties of a zinc(II) complex with the lapacholate anion and ethanol as ligands; Taylor & Francis Ltd; Journal of Coordination Chemistry; 56; 9; 6-2003; 803-816
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