Artículo
Complexation, adsorption and reduction of palladium-dimethylglyoxime: analytical considerations.
Fecha de publicación:
07/2010
Editorial:
Simplex Academic Publishers
Revista:
Global Journal of Analytical Chemistry
ISSN:
0976-5514
e-ISSN:
0976-6030
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Electroanalysis offers an interesting tool for palladium quantification by using adsorptive stripping voltammetry of Pd-dimethylglioxime complex on mercury . Here we show that complexation kinetics and solubility in the homogeneous phase, in addition to surface concentration, are relevant analytical aspects to be considered. Complexation kinetics is first order in both Pd(II) and the ligand (k = 15 s-1M-1 ). This determines the chemical equilibration time after each metal addition: for example when using 1 x 10-4 M H2DMG a non negligible chemical equilibration time ca. 1 hour should be considered. The upper limit of the linear range is determined by two factors: complex solubility in the solution (ca. 2.5 μM) and surface concentration. The latter should develop a redox charge lower than 30 μC cm-2 .
Palabras clave:
Palladium
,
Dimethylglyoxime
,
Adsorption
,
Stripping Voltammetry
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(INQUIMAE)
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Citación
Ramírez, Silvana Andrea María; Gordillo, Gabriel Jorge; Complexation, adsorption and reduction of palladium-dimethylglyoxime: analytical considerations.; Simplex Academic Publishers; Global Journal of Analytical Chemistry; 1; 1; 7-2010; 59-67
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