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dc.contributor.author
López García, José Juan  
dc.contributor.author
Horno José  
dc.contributor.author
Grosse, Constantino  
dc.date.available
2019-02-13T17:27:19Z  
dc.date.issued
2011-12  
dc.identifier.citation
López García, José Juan; Horno José; Grosse, Constantino; Poisson-Boltzmann description of the electrical double layer including ion size effects; American Chemical Society; Langmuir; 27; 23; 12-2011; 13970-13974  
dc.identifier.issn
0743-7463  
dc.identifier.uri
http://hdl.handle.net/11336/70073  
dc.description.abstract
The electrical double layer is examined using a generalized Poisson-Boltzmann equation that takes into account the finite ion size by modeling the aqueous electrolyte solution as a suspension of polarizable insulating spheres in water. We find that this model greatly amplifies the steric effects predicted by the usual modified Poisson-Boltzmann equation, which imposes only a restriction on the ability of ions to approach one another. This amplification should allow for an interpretation of the experimental results using reasonable effective ionic radii (close to their well-known hydrated values).  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
American Chemical Society  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Colloids  
dc.subject
Double Layer  
dc.subject
Poisson-Boltzmann  
dc.subject
Finite Ion Size  
dc.subject.classification
Astronomía  
dc.subject.classification
Ciencias Físicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Poisson-Boltzmann description of the electrical double layer including ion size effects  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2019-02-12T14:11:37Z  
dc.journal.volume
27  
dc.journal.number
23  
dc.journal.pagination
13970-13974  
dc.journal.pais
Estados Unidos  
dc.journal.ciudad
Washington DC  
dc.description.fil
Fil: López García, José Juan. Universidad de Jaén; España  
dc.description.fil
Fil: Horno José. Universidad de Jaén; España  
dc.description.fil
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina  
dc.journal.title
Langmuir  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1021/la2025445  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/la2025445