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dc.contributor.author
Grosse, Constantino  
dc.date.available
2019-02-13T17:24:47Z  
dc.date.issued
2011-07  
dc.identifier.citation
Grosse, Constantino; Extension of a classic thin double layer polarization theory of colloidal suspensions to include the stagnant layer conductivity; American Chemical Society; Journal of Physical Chemistry B; 115; 29; 7-2011; 8996-9004  
dc.identifier.issn
1520-6106  
dc.identifier.uri
http://hdl.handle.net/11336/70072  
dc.description.abstract
A rigorous extension of the classic Dukhin-Shilov thin double layer polarization theory including the stagnant layer conductivity is presented. Precisely the same assumptions and approximations made in the original theory are maintained, and the same adsorption isotherms are used as in most of the existing numerical calculations. The obtained analytical results improve upon existing approximate extensions, mainly for low surface conductivities and high surface potentials and for high surface conductivities and low surface potentials. Moreover, they avoid the assumption that all the adsorbed ions in the stagnant layer must have a single sign. Finally, they present a very good agreement with numerical calculations specifically made using the same system parameters.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
American Chemical Society  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Colloidal Dispersions  
dc.subject
Stagnant Layer Conductivity  
dc.subject
Stern Layer Conductivity  
dc.subject
Anomalous Conductivity  
dc.subject.classification
Astronomía  
dc.subject.classification
Ciencias Físicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Extension of a classic thin double layer polarization theory of colloidal suspensions to include the stagnant layer conductivity  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2019-02-12T14:11:33Z  
dc.journal.volume
115  
dc.journal.number
29  
dc.journal.pagination
8996-9004  
dc.journal.pais
Estados Unidos  
dc.journal.ciudad
Washington DC  
dc.description.fil
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina  
dc.journal.title
Journal of Physical Chemistry B  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1021/jp203156w  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/jp203156w